在离子液超电容器中对离子动力学和电荷存储的NMR研究
Alexander C Forse1, John M Griffin1, Céline Merlet1
1†Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom.
Journal of the American Chemical Society
|May 15, 2015
概括
核磁共振 (NMR) 揭示了离子液体如何充电超级电容器. 碳孔内的阳离子吸附和脱附是充电动态的关键,解释了功率性能差异.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 物理化学 物理化学
背景情况:
- 离子液体为超级电容器提供高能量密度,这是由于更高的操作电压.
- 目前的功率性能限制需要对电荷存储机制进行基础研究.
研究的目的:
- 为了研究有孔碳电极内的离子液体的结构和动力学.
- 阐明电荷储存机制和影响超级电容器中离子扩散的因素.
主要方法:
- 核磁共振 (NMR) 光谱学的应用.
- 在孔隙碳电极中封闭的离子液体的现场分析.
主要成果:
- 离子液体自发湿碳微孔.
- 超级电容器充电涉及对电离子吸附和共电离子脱吸,其中离子起着主导作用.
- 核磁共振线形状分析探测离子扩散率,受离子液体类型和溶剂添加剂的影响.
结论:
- 超级电容器中离子液体充电机制的解.
- 核磁共振对影响离子扩散和超级电容器功率性能的因素提供了洞察力.
- 了解这些动态可以指导改进的离子液体电解质的开发.
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