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使用金属有机框架从水中吸附和去除酸盐和酸盐的高效率吸附和去除

Ashlee J Howarth1, Michael J Katz1, Timothy C Wang1

  • 1†Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United States.

Journal of the American Chemical Society
|May 23, 2015
PubMed
概括

基于的金属有机框架 (MOF) 被评估为从水中去除. 在吸附酸盐和酸盐方面,NU-1000表现出卓越的性能,显示出高容量和快速吸收.

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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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