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Updated: Apr 7, 2026

Atomic Scale Structural Studies of Macromolecular Assemblies by Solid-state Nuclear Magnetic Resonance Spectroscopy
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确定 σ 和 π 合的 conformational 景观 使用 para-Phenylene 和"Aviram-Ratner"桥梁

Daniel E Stasiw1, Jinyuan Zhang1, Guangbin Wang1

  • 1†Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, United States.

Journal of the American Chemical Society
|July 9, 2015
PubMed
概括

我们量化了分子结构如何影响捐赠者-桥梁-接受器系统中的电子合. 在桥上放置甲基组揭示了对磁交换的显著sigma和pi轨道贡献,这对分子电子学至关重要.

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