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降低CO2功能的N-异环碳素的真正作用:密度功能理论研究的替代理解

Qinghai Zhou1, Yuxue Li1

  • 1State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China.

Journal of the American Chemical Society
|July 30, 2015
PubMed
概括

N-异环碳素 (NHC) 作为离子液体催化剂的前体,使CO2具有高效的还原功能. 新的S(N) 2@Si受体机制降低了二氧化碳转化为甲胺或甲醇的能量障碍.

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