微粒结构和疏水性水分
Joshua A Long1, Blake M Rankin1, Dor Ben-Amotz1
1Department of Chemistry, Purdue University , West Lafayette, Indiana 47907, United States.
Journal of the American Chemical Society
|July 30, 2015
概括
水深入表面活性剂, 挑战以前的模型. 这项研究揭示了小胞内部的水化腔,表明类似蛋白质的复杂结构.
科学领域:
- 物理化学
- 超分子化学
- 光谱学
背景情况:
- 菌根是水溶液中表面活性剂形成的无处不在的自组结构.
- 了解体内部水分和表面结构对于应用至关重要,但仍然具有挑战性.
- 之前的模型通常假设更刚性和更少的疏水核心.
研究的目的:
- 研究具有不同链条长度和头部组的表面活性剂菌体的疏水.
- 为了确定水透到菌内部的程度.
- 描述微粒内的溶解分子的微环境.
主要方法:
- 具有多变量曲线分辨率的组合拉曼光谱 (Raman-MCR).
- 探测的表面活性剂具有不同的亚利法链长度和阳离子 (碳酸盐) 或阴离子 (三甲) 头组.
- 研究的系统在临界菌度 (CMC) 以下和以上.
主要成果:
- 显著的水透到内部,延伸到头组附近的前几颗碳.
- 溶解脱的n-hexane显示振动CD频率的变化表明一个干燥的,油性环境.
- 发现溶解的局部对头组电荷敏感.
结论:
- 微粒的疏水芯被波纹表面包围,带有水合的非极性腔.
- 这些水化腔的深度随着表面活性剂链的长度而增加.
- 这些发现表明细胞结构比以前认为的更加复杂和类似蛋白质.
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