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Updated: Apr 6, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

Published on: February 15, 2016

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超原子6电子和8电子配置的M@Au24(SR) 18集群之间的相互转换 (M = Pd, Pt)

Kyuju Kwak1, Qing Tang2, Minseok Kim1

  • 1Department of Chemistry, Yonsei University , Seoul 120-749, Korea.

Journal of the American Chemical Society
|July 30, 2015
PubMed
概括

用或添加的硫酸盐保护黄金集群表现出稳定的6电子配置,与纯金集群的8电子配置不同. 这种兴奋剂显著减少了最高占成的分子轨道 - 最低的未占用的分子轨道间隙,改变了电子结构.

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