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在添加的纳米钻石上将二氧化碳有效电化学降解为乙酸盐

Yanming Liu1, Shuo Chen1, Xie Quan1

  • 1Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), School of Environmental Science and Technology, Dalian University of Technology , Dalian 116024, China.

Journal of the American Chemical Society
|September 1, 2015
PubMed
概括

这项研究引入了N-doped nanodiamond/Si rod array (NDD/Si RA) 作为一种非金属电催化剂,用于高效的二氧化碳 (CO2) 减少,选择性地将CO2转化为酸盐.

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Preparation of Aldehydes and Ketones from Nitriles and Carboxylic Acids01:24

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Although it is possible to reduce a carboxylic acid to an aldehyde, strong reducing agents, like lithium aluminum hydride (LAH), prohibit a controlled reduction, instead causing the generated aldehyde to instantly over-reduce to a primary alcohol.
Reducing carboxylic acid derivatives like acyl chlorides (RCOCl), esters (RCO2R′), and nitriles (RCN) using milder aluminum hydride agents like lithium tri-tert-butoxyaluminum hydride [LiAlH(O-t-Bu)3] and diisobutylaluminum hydride [DIBAL-H]...
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