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相关概念视频

Ionic Crystal Structures02:42

Ionic Crystal Structures

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Phase Transitions

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Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to...
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Phase Transitions01:21

Phase Transitions

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A phase transition is the process in which a substance changes from one state of matter to another, like from a solid to a liquid, liquid to gas, or vice versa, at a specific temperature and under given pressure conditions. This change is spontaneous and is affected by alterations in temperature and pressure. These parameters impact the strength of the forces between molecules (intermolecular forces) in the substance.During a phase transition, both the initial and final phases of the substance...
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Phase Transitions: Melting and Freezing02:39

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Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
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Metallic Solids02:37

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
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Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
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High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal
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由柱状液晶中的矩形-六角相变引起的离子开关

Bartolome Soberats1,2, Masafumi Yoshio1, Takahiro Ichikawa3

  • 1Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.

Journal of the American Chemical Society
|September 30, 2015
PubMed
概括

液晶盐的离子导电性可以通过相位过渡来切换. 由于离子通道结构,六角柱状相比矩形柱状相具有显著的导电性.

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科学领域:

  • 材料科学
  • 物理化学
  • 晶体学

背景情况:

  • 液晶具有独特的自组合特性.
  • 材料中的离子导电性对于储能和电子来说至关重要.
  • 控制有序软材料中的离子传输仍然是一个挑战.

研究的目的:

  • 为了证明形液晶盐的离子导电性的切换.
  • 研究液晶相与离子运输之间的关系.
  • 了解导电性调节的结构基础.

主要方法:

  • 合成形液晶盐
  • 矩形柱状 (Colr) 和六角柱状 (Colh) 阶段之间的相变的热力学控制.
  • 离子导电性测量
  • 进行X射线衍射实验以分析结构变化.

主要成果:

  • 在导电性切换中成功使用了Collr和Collh相之间的热可逆相过渡.
  • 科尔赫阶段的离子导电率大约是科尔尔阶段的四个数量级.
  • X射线实验揭示了Colr阶段高度有序的离子包装,阻碍了离子运输,而Colh阶段则促进了这种情况.

结论:

  • 在液晶盐中通过利用相位过渡实现了可切换的离子导电性.
  • 观察到的导电性切换归因于离子通道在相位过渡期间的结构重排.
  • 这些发现为设计具有可调节性质的先进离子导电材料提供了途径.