可在水中分散,响应和可碳化的毛状微孔聚合物纳米圈
Weicong Mai1, Bin Sun1, Luyi Chen1
1Materials Science Institute, Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-sen University , Guangzhou 510275, P. R. China.
Journal of the American Chemical Society
|October 2, 2015
概括
研究人员开发了新的毛的微孔聚合物纳米圈, 这些多功能纳米颗粒可以很容易地被碳化成精确的微孔碳纳米圈,用于先进的应用.
科学领域:
- 材料科学
- 聚合物化学
- 纳米技术
背景情况:
- 微孔聚合物通常具有疏水性,并且缺乏对环境刺激的反应性.
- 目前碳化微孔聚合物的方法往往会损害它们的纳米形态.
- 微孔聚合物的多功能化是材料科学中的一个重大挑战.
研究的目的:
- 为制造多功能毛的微孔聚合物纳米球开发一种简单多功能的方法.
- 创建具有水分散性,对pH值和温度有反应性,易于碳化的材料.
- 克服当前疏水和无反应的微孔聚合物的局限性.
主要方法:
- 使用超交叉链化学和表面启动原子转移基聚合 (SI-ATRP) 的组合制造毛的微孔聚合物纳米球.
- 用SI-ATRP将多种功能块移植到表面, 形成毛的结构.
- 由此产生的纳米球因其特性和响应性的特征.
主要成果:
- 成功合成了水分散性,pH/温度敏感的毛的微孔聚合物纳米球.
- 纳米球对水溶液吸附物的高吸附能力.
- 通过混合核心外结构的碳化,展示了将这些纳米球转化为明确的微孔碳纳米球的能力.
结论:
- 拟议的战略提供了一种多功能的微孔聚合物方法.
- 发育的毛纳米球具有理想的特性,包括响应能力和高吸附能力.
- 这种方法有助于创建先进的微孔碳纳米结构,促进各种领域的应用.
更多相关视频
相关概念视频
Colloids
17.2K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.2K
Colloidal precipitates
5.7K
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
5.7K
Coagulation
1.5K
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
1.5K
The Colloidal State
184
The formation of a colloidal system is exemplified by an aqueous solution containing Cl− ions is introduced to another containing Ag+ ions, resulting in the precipitation of solid AgCl as extremely tiny crystals. Instead of settling out as a filterable precipitate, these crystals remain suspended in the liquid, showcasing a colloidal system.A colloidal system involves colloidal particles within the approximate range of 1 to 1000 nm in at least one dimension, dispersed in a medium called...
184
Micelles
364
Micelle formation is an intricate process that hinges on the properties of amphiphilic or amphipathic molecules and the conditions of the system in which they are found. Amphiphilic molecules, which have both hydrophilic (water-attracting) and hydrophobic (water-repelling) parts, play a critical role in this process.In aqueous environments, these molecules arrange themselves such that their hydrophilic heads are turned towards the water phase, while their hydrophobic tails are oriented away...
364
Microbial Mats
67
Microbial communities forming biofilms and mats represent complex, spatially structured ecosystems where metabolic processes are stratified according to light, oxygen, and nutrient gradients. Biofilms are initial colonization stages, only a few millimeters thick, while mature microbial mats can reach centimeter-scale thickness and display intricate vertical organization. Their structural and functional heterogeneity allows microorganisms to occupy distinct ecological niches within a few...
67


