设计的非对称异质膜:度梯度驱动的能量采集装置
Zhen Zhang, Xiang-Yu Kong, Kai Xiao
1Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Key Laboratory of Theoretical and Computational Photochemistry, Ministry of Education, Beijing Normal University , Beijing 100875, P. R. China.
Journal of the American Chemical Society
|November 5, 2015
概括
具有块共聚物 (BCP) 的工程膜具有高离子选择性和离子整形. 这一突破使电化学梯度能有效地转化能量, 进步纳米流体和生物传感器.
科学领域:
- 材料科学
- 纳米技术
- 化学工程
背景情况:
- 设计的不对称膜对于纳米级分子和离子运输控制至关重要.
- 开发具有选择性和整形离子传输的高性能异质膜是可取的.
- 模仿生物通道需要多功能和工程方法.
研究的目的:
- 设计具有优异的离子选择性和离子整形的不对称异质膜.
- 使用这种膜从电化学度梯度转换能量.
- 在纳米流体系统中探索多功能块共聚物 (BCP) 的潜力.
主要方法:
- 组合一个多孔块共聚物 (BCP) 膜 (聚乙烯-多聚) 与一个带有轨迹的不对称多孔聚乙烯甲酸盐膜.
- 将化学,几何和静电结构引入膜.
- 开发使用阳离子选择性异质膜的能量转换装置.
主要成果:
- 实现了极好的离子选择性和超高的离子校正,比率约为1075.
- 从电化学度梯度中获得有效的能量.
- 消除了能量转换装置中的度极化,增加了输出功率密度.
结论:
- 设计的非对称异质膜为纳米流体系统提供了一个新范式.
- 多功能BCP可以有效地用于先进的膜应用.
- 这项工作为化学,材料科学,生物科学和纳米技术的突破打开了前途.
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