通过时间解析振动光谱学揭示了水-表面活性剂界面上的两种水
Ruth A Livingstone1, Yuki Nagata1, Mischa Bonn1
1Max Planck Institute for Polymer Research , Ackermannweg 10, 55128 Mainz, Germany.
Journal of the American Chemical Society
|November 7, 2015
概括
二硫酸盐 (SDS) 改变了水的结构. 在SDS表面活性剂附近,光谱分析显示了两种不同的合水子组,具有独特的结特性.
科学领域:
- 表面化学
- 物理化学
- 光谱学
背景情况:
- 二硫酸盐 (SDS) 是用于洗剂的常见表面活性剂.
- 表面活性剂在接口上形成自我组装的单层,影响周围的分子.
- 了解水和表面活性剂的相互作用对于各种应用至关重要.
研究的目的:
- 在接口上开发SDS-水相互作用的显微模型.
- 调查SDS附近的水分子的结特性.
- 将SDS与水接口的水结构与空气-水接口进行比较.
主要方法:
- 静态和时间分辨率的二维总频率生成 (2D-SFG) 光谱.
- 对O-H拉伸振动进行分析,以探测水结构.
- 对界面相互作用的微观建模.
主要成果:
- 在SDS头部附近确定了两个不同的水分组.
- 在SDS头部附近观察到局部的OH拉伸振动.
- 在其他水分子中检测到O-H延伸振动.
- 在这两个水子集之间显示了亚皮秒能量传输.
- 证明与SDS相互作用的水与散装水具有不同的结特性.
结论:
- 在SDS附近的水分子表现出异质的结特性.
- 已识别的水子集是合的,促进了快速的能量传输.
- 在接口上,SDS显著改变了水的结网络,与空气-水接口不同.
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