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In Situ Synthesis of Gold Nanoparticles without Aggregation in the Interlayer Space of Layered Titanate Transparent Films
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对AU纳米颗粒的乳腺-晶合成的电化学洞察

Akihiro Uehara1, Samuel G Booth, Sin Yuen Chang

  • 1Division of Nuclear Engineering Science, Research Reactor Institute, Kyoto University , Asashironishi, Kumatori, Osaka 590-0494, Japan.

Journal of the American Chemical Society
|November 13, 2015
PubMed
概括

金纳米颗粒的Brust-Schiffrin合成涉及到在有机溶剂中通过BH4减少[AuCl4]-]. 产品的形成,包括[AuCl2](-) 和Au(I) SR,取决于硫醇与黄金的比例和时间.

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Imperfections in Crystal Structure: Stoichiometric Point Defects01:26

Imperfections in Crystal Structure: Stoichiometric Point Defects

Schottky defects arise when some lattice points in a crystal, such as those in NaCl, remain unoccupied, creating lattice vacancies without disturbing the overall electrical neutrality of the crystal. This defect is common in ionic crystals where the positive and negative ions are similar in size, as seen in sodium chloride and cesium chloride. The presence of Schottky defects enables the crystal to conduct electricity to a small extent through an ionic mechanism. Electric fields cause nearby...
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