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相关概念视频

Porosity in Cement Paste01:18

Porosity in Cement Paste

553
The porosity of concrete is a measure of the void spaces within its structure. These spaces impact its strength and durability significantly. When water and cement interact, a chemical reaction called hydration creates a semi-solid paste. This paste includes combined water, making up approximately 23% of the cement's dry mass, and gel water, which fills minuscule voids known as gel pores, accounting for about 28% of the cement gel volume.
The balance of water to cement in the mix is...
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Permeability of Concrete01:25

Permeability of Concrete

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Permeability in the context of concrete refers to how easily liquids or gases can pass through the material. This quality is crucial for assessing the water-tightness and durability of concrete structures and their resistance to chemical attacks. Concrete permeability can be determined through comparative laboratory tests. These tests typically involve sealing a concrete specimen from the sides, applying water pressure to the top surface with pressure, and measuring the amount of water passing...
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Total Voids in Concrete01:12

Total Voids in Concrete

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Total voids in concrete encompass gel water volume, capillary pores, and entrapped air. Gel water (retained within the cement hydration products) and physically entrapped or adsorbed water are significant for the hydration process. For complete hydration, it's estimated that the space needed for the products of a cubic centimeter of cement doubles. Capillary pores constitute the unoccupied space within the hydrated cement paste, with their size largely influenced by the water-to-cement...
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Porosity and Absorption of Aggregate01:20

Porosity and Absorption of Aggregate

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Aggregates contain pores of varying sizes; while some are completely enclosed within the particles, others open onto the surface, allowing water to penetrate. The porosity of aggregates is a major factor contributing to the overall porosity of concrete, given that aggregates constitute about three-quarters of concrete's volume.
When all pores in an aggregate are filled with water, the aggregate is considered saturated and surface-dry. If left in dry air, water will evaporate until the...
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Types of Fluids01:27

Types of Fluids

1.2K
Fluids can be classified into Newtonian and non-Newtonian fluids based on their response to shear stress. Newtonian fluids have a linear relationship between shear stress and the shear strain rate, following Newton's law of viscosity. Their viscosity remains constant regardless of the shear rate, making their behavior predictable and easier to analyze. Common examples include water, air, oil, and gasoline.
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Characteristics of Fluids01:20

Characteristics of Fluids

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When a force is applied parallel to the top surface of a solid, it resists the applied force due to the internal frictional forces between the layers of the solid known as shearing resistance. However, when the force is removed, the shearing forces restore the original shape of the solid. Other deformation forces also cause temporary changes in shape if the forces are not beyond a threshold magnitude. Solids tend to retain their shape, making the study of their rest and motion easier. Beyond...
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相关实验视频

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Microfluidic Devices for Characterizing Pore-scale Event Processes in Porous Media for Oil Recovery Applications
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具有永久多孔性的液体

Nicola Giri1, Mario G Del Pópolo2,3, Gavin Melaugh2

  • 1School of Chemistry and Chemical Engineering, Queen's University Belfast, David Keir Building, Stranmillis Road, Belfast BT9 5AG, UK.

Nature
|November 13, 2015
PubMed
概括

研究人员开发出具有永久多孔性的自由流动液体, 克服固体材料的局限性, 这些新的多孔液体在化学过程和气体溶解性方面具有显著的优势.

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科学领域:

  • 材料科学
  • 化学工程
  • 超分子化学

背景情况:

  • 化物和金属有机框架等多孔固体对于分离和催化有价值,但在常规流系统中面临实施挑战.
  • 由于更容易融入现有基础设施,一些应用,如二氧化碳捕获,更喜欢液态溶剂.
  • 一个关键的挑战是,在先进的化学过程中,将流动性与永久性孔隙性结合起来.

研究的目的:

  • 通过永久的孔隙性来产生自由流动的液体.
  • 开发新的多孔材料,克服传统固体吸附剂的局限性.
  • 在分子分离,催化和气体储存方面实现新的可能性.

主要方法:

  • 具有明确孔隙的子分子的设计.
  • 子分子在溶剂中的高溶解度太大,无法进入毛孔.
  • 从商业试剂中合成高度溶解的"混"多孔.

主要成果:

  • 实现了高度的空 (约. 比传统的解决方案大500倍.
  • 证明甲气体的可溶性增加了8倍.
  • 开发了一个可扩展的,单步合成路径,用于多孔液体材料.

结论:

  • 引入了一类新的功能性多孔材料:自由流动的多孔液体.
  • 设计原则侧重于对溶剂不溶的子分子,防止孔隙透.
  • 这些材料为先进的化学分离和工艺提供了有前途的平台.