Pd@Pt核心形十面体:一种具有增强活性和耐久性的氧降解反应催化剂
Xue Wang1,2, Madeline Vara3, Ming Luo1
1The Wallace H. Coulter Department of Biomedical Engineering, Georgia Institute of Technology and Emory University , Atlanta, Georgia 30332, United States.
Journal of the American Chemical Society
|November 14, 2015
概括
我们开发了一种新的- (Pd@Pt) 核心形十面体的合成方法. 与商业催化剂相比,这些新型催化剂显著提高了氧降解反应 (ORR) 的活性和耐用性.
科学领域:
- 材料科学
- 纳米技术
- 催化剂
背景情况:
- 开发高效的电催化剂对于能源转换技术至关重要.
- - (Pd@Pt) 核心外纳米结构对催化有希望.
- 控制纳米粒子形态会影响催化性能.
研究的目的:
- 合成多个双胞胎Pd@Pt核心形十面体.
- 研究十面体种子形态对Pt沉积的影响.
- 评估合成的Pd@Pt形十面体的催化活性和耐久性,用于氧降解反应 (ORR).
主要方法:
- 通过对Pd十面体种子进行受控的Pt沉积,轻松合成Pd@Pt核心的形十面体.
- 原子沉积和扩散在十面表面的特征.
- 使用循环电压测量和加速耐久性测试进行ORR活性和耐久性的电催化测试.
主要成果:
- 成功合成了Pd@Pt核心形十面体,其中Pt优先沉积在高能点 (顶点,边缘/斜坡) 上.
- 与商业Pt/C相比,形十面体在ORR的特定活性增加了4.4倍,质量活性增加了6.6倍.
- 催化剂在10000个耐用周期后保持了Pt/C的两倍以上的质量活性.
结论:
- 控制合成策略为ORR产生高度活跃和持久的Pd@Pt形十面体.
- 独特的状十面体形态和核心外结构有助于增强催化性能.
- 这些发现为设计先进的电催化剂提供了有前途的途径.
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