证据表明密度超过325千兆帕斯卡的新阶段
Philip Dalladay-Simpson1, Ross T Howie1, Eugene Gregoryanz1,2
1School of Physics and Centre for Science at Extreme Conditions, University of Edinburgh, Edinburgh EH9 3JZ, UK.
Nature
|January 8, 2016
概括
研究人员在超过325千兆帕斯卡的极端压力下观察到分子 (H2) 和二 (HD) 的新阶段 (V阶段). 这一发现为密集及其潜在的金属状态提供了洞察力.
科学领域:
- 高压物理
- 材料科学
- 量子化学
背景情况:
- 压缩下原子金属的理论预测可以追溯到80年前.
- 在高压研究中, 实现这种状态是三十年来最大的挑战.
- 了解在极端压力下的行为对于凝聚物质物理学来说至关重要.
研究的目的:
- 在极端压缩下实验性地识别和二的新相.
- 在压力超过325千兆帕斯卡尔时描述的物理性质.
- 研究对相转换的同位素效应.
主要方法:
- 在现场使用高压拉曼光谱来研究及其同位素.
- 在高达388GPa的压力和高达465K的温度下进行了实验.
- 通过振动拉曼活动和激发频率的变化来确定相位过渡.
主要成果:
- 在H2和HD中观察到一个新的阶段,称为V阶段,在300K时超过325GPa.
- 第五阶段的特征是拉曼活性减弱,振动频率的压力依赖性改变,以及低频激发的丧失.
- 在D2中没有观察到V阶段,而在300K时转化为4阶段'超过310GPa,表明显著的同位素效应.
结论:
- 这项研究为和二的第一个实验证据提供了.
- 这些发现限制了V阶段的压力-温度条件,并突出了显著的同位素变化.
- 第五阶段被认为是长期预测的原子金属状态的潜在前体.
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