用于分离六化硫的有机
Tom Hasell1, Marcin Miklitz2, Andrew Stephenson1
1Department of Chemistry and Centre for Materials Discovery, University of Liverpool , Crown St., Liverpool L69 7ZD, United Kingdom.
Journal of the American Chemical Society
|January 14, 2016
概括
研究人员发现了一个多孔的有机,CC3,对硫六化物 (SF6) 具有异常的选择性. 这一突破为环境条件下高效的气体分离提供了一种新材料.
科学领域:
- 材料科学
- 化学工程
- 吸附科学
背景情况:
- 硫六化物 (SF6) 的选择性吸附对于环境修复和工业过程至关重要.
- (N2) 是气流中常见的成分,需要选择性去除SF6.
- 现有的材料通常需要特定的条件或具有SF6/N2选择性的限制.
研究的目的:
- 调查一系列多孔有机对N2的选择性SF6吸附.
- 在环境温度和压力下识别具有高SF6/N2选择性的材料.
- 了解观察到的吸附行为背后的机制.
主要方法:
- 对有孔的有机进行SF6/N2选择性的选.
- 气体突破实验用于现实世界分离评估.
- 用于确定SF6在中的位置的X射线晶体学.
- 吸附异热和孔隙结构的分析.
主要成果:
- 一个多孔的有机,CC3,在环境条件下显示出最高的SF6/N2选择性.
- 在气体突破柱实验中,CC3实现了有效的SF6分离.
- 观察到的SF6吸收超过了基于静态孔隙结构的预测.
- X射线结晶学揭示了SF6的位置,并表明了协同扩散和结构重组.
结论:
- 有孔的有机,特别是CC3,对选择性捕获SF6非常有希望.
- 观察到的高选择性归因于合作扩散和结构重组等动态过程,而不仅仅是静态孔径大小.
- 这些发现为开发高效的SF6分离和环境应用的先进材料铺平了道路.
相关概念视频
Exceptions to the Octet Rule
38.7K
Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
38.7K
Supercritical Fluid Chromatography
1.3K
Supercritical fluid chromatography (SFC) provides a beneficial substitute for gas chromatography (GC) and liquid chromatography (LC) for certain samples because it merges the top attributes of both techniques. SFC allows the separation and analysis of compounds that GC or LC does not easily manage. These compounds are traditionally nonvolatile or thermally unstable, making GC unsuitable and lacking functional groups required for HPLC analysis.
SFC utilizes a supercritical fluid mobile phase,...
SFC utilizes a supercritical fluid mobile phase,...
1.3K
Size-Exclusion Chromatography
2.6K
In size-exclusion chromatography (SEC), also known as molecular-exclusion or gel-permeation chromatography, molecules are separated based on their sizes. This technique is important for separating large molecules such as polymers and biomolecules. The two classes of micron-sized stationary phases encountered in SEC are silica particles and cross-linked polymer resin beads. Both materials are porous, but their pore sizes vary significantly.
Silica particles offer advantages such as rigidity,...
Silica particles offer advantages such as rigidity,...
2.6K
Hybridization of Atomic Orbitals II
50.3K
sp3d and sp3d 2 Hybridization
50.3K
Preparation and Reactions of Sulfides
6.0K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
6.0K
VSEPR Theory and the Basic Shapes
87.4K
Overview of VSEPR Theory
87.4K


