一个{Mn(II) 15Mn(III) 4}布鲁岩盘的层次组合:逐步形成和铁磁
Yong-Kai Deng1, Hai-Feng Su2, Jia-Heng Xu1
1Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University , Jinan 250100, P. R. China.
Journal of the American Chemical Society
|January 19, 2016
概括
研究人员详细介绍了团的逐步组装,从单体到Mn19盘. 这种功能性分子材料表现出低于40K的铁磁性行为,这是非连接的高旋转分子的罕见属性.
科学领域:
- 协调化学
- 材料科学
- 超分子化学
背景情况:
- 研究功能分子材料及其形成机制对于开发先进材料至关重要.
- 层次的自我组装过程是构建复杂分子架构的关键.
- 了解多核金属复合体中的结构属性关系是一个活跃的研究领域.
研究的目的:
- 阐明从单体到六合体和非十合体的团的逐步形成机制.
- 描述一个功能分子材料Mn19盘的结构和特性.
- 研究合成的Mn19集群的磁性行为和电化学.
主要方法:
- 使用高分辨率电喷离子质谱 (HRESI-MS) 识别中间集群和最终的Mn19产品.
- 单晶X射线衍射被用来确定Mn19星团的晶体结构,揭示了光盘形状.
- 进行磁性测量 (磁化,强迫场) 和电化学研究材料的行为.
主要成果:
- 从单体 (Mn) 到体 (Mn7) 到非体 (Mn19) 的层次形成路径是按照1 + Σn6n的关系建立的.
- 在形成过程中确定了三个中间集群 (Mn10,Mn12,Mn14).
- 磁铁磁盘的公式为[Mn19(L) x ((OH) y ((N3) 36-x-y] ((2+),具有混合价值状态 ([Mn ((II) 15Mn ((III) 4)) 并表现为40K以下的铁磁铁,其强迫场在1.8K时为2.7kOe.
结论:
- 这项研究成功阐明了团的逐步形成,从而形成了功能性Mn19盘.
- Mn19磁盘显示出一种罕见的磁性排序 (铁磁性) 来自不连接的高旋转分子.
- 观察到的磁性归因于微弱的分子间交换相互作用或透过空间的双极相互作用.
更多相关视频
相关概念视频
Metallic Solids
21.3K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
21.3K
Ionic Crystal Structures
20.5K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
20.5K
Lattice Centering and Coordination Number
15.1K
The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...
Types of Unit Cells
Imagine taking a large number of identical...
15.1K
Assembly of Complex Microtubule Structures
2.8K
Complex microtubule structures are present in resting cells and in dividing cells. In resting cells, they are responsible for maintaining the cellular architecture, tracks for intracellular transport, positioning of organelles, assembly of cilia and flagella. They mediate the bipolar spindle assembly for chromosomal segregation and positioning of the cell division plate in dividing cells. The formation of microtubule complex structures depends on the cell type, cell stage, and cell function.
2.8K
Valence Bond Theory
11.6K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
11.6K
Crystal Field Theory - Octahedral Complexes
31.7K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
31.7K


