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相关概念视频

Molecules and Compounds02:38

Molecules and Compounds

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Atoms and Molecules
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Chemical Bonds02:40

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Atoms participate in a chemical bond formation to acquire a completed valence-shell electron configuration similar to that of the noble gas nearest to it in atomic number. Ionic, covalent, and metallic bonds are some of the important types of chemical bonds. Bond energy and bond length determine the strength of a chemical bond.
Types of Chemical Bonds
An ionic bond is formed due to electrostatic attraction between cations and anions. Often, the ions are formed by the transfer of electrons...
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Covalent Bonds01:08

Covalent Bonds

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Overview
When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
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Covalent Bonds

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Covalent Bonding and Lewis Structures02:46

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Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
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Introduction to Chemical Bonds01:01

Introduction to Chemical Bonds

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Chemical Bonds
The electrons of the outermost energy level determine the energetic stability of the atom and its tendency to form chemical bonds with other atoms. The innermost electron shell has a maximum capacity of two electrons, but the next two electron shells can each have a maximum of eight electrons. This is known as the octet rule, which states that, with the exception of the innermost shell, atoms are most stable energetically when they have eight electrons in their valence shell, the...
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相关实验视频

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超出分子的共价化学

Juncong Jiang1, Yingbo Zhao1, Omar M Yaghi1,2

  • 1Department of Chemistry, University of California-Berkeley, Materials Sciences Division, Lawrence Berkeley National Laboratory, and Kavli Energy NanoSciences Institute at Berkeley , Berkeley, California 94720, United States.

Journal of the American Chemical Society
|February 11, 2016
PubMed
概括

共价有机框架 (COF) 和金属有机框架 (MOF) 允许精确地构建晶体延伸结构. 这些先进的材料提供可调节的孔隙性和化学功能的各种应用.

科学领域:

  • 材料科学
  • 化学学
  • 纳米技术

背景情况:

  • 传统上,共价化学专注于离散分子.
  • 将分子单元连接成晶体固体是一个重要的结晶挑战.
  • 金属有机框架 (MOF) 和共价有机框架 (COF) 代表了范式的转变,将共价化学扩展到扩展结构.

研究的目的:

  • 突出在MOF和COF合成中克服结晶问题的策略的发展.
  • 展示结晶延伸结构产生的独特特性和应用.
  • 强调MOF和COF在创造具有设计孔隙性和化学复杂性的功能材料方面的潜力.

主要方法:

  • 合成策略的开发,以克服形成共价固体的结晶问题.
  • 使用大型分子构建单元来创建开放的晶体框架.
  • 在合成后对MOF和COF进行共价功能化,以引入化学复杂性.

主要成果:

  • 成功合成了许多具有可调节孔隙性的晶体MOF和COF.
  • 在框架上证明共价反应,保持结晶性和多孔性.
  • 创建定义良好的中镜结构,例如包围无机纳米晶体的纳米MOF,增强它们的特性.

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结论:

  • MOF和COF可以精确控制框架架构,孔径和功能.
  • 这些材料为先进的化学合成和材料设计提供了平台.
  • 进行合成后改造的能力为创建具有定制性质的新功能材料开辟了道路.