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相关概念视频

Types of Chemical Bonds02:37

Types of Chemical Bonds

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Chemical bonding theories were pioneered by American chemist Gilbert N. Lewis. He developed a model called the Lewis model to explain the type and formation of different bonds. Chemical bonding is central to chemistry; it explains how atoms or ions bond together to form molecules. It explains why some bonds are strong and others are weak, or why one carbon bonds with two oxygens and not three; why water is H2O and not H4O. 
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Atoms participate in a chemical bond formation to acquire a completed valence-shell electron configuration similar to that of the noble gas nearest to it in atomic number. Ionic, covalent, and metallic bonds are some of the important types of chemical bonds. Bond energy and bond length determine the strength of a chemical bond.
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An ionic bond is formed due to electrostatic attraction between cations and anions. Often, the ions are formed by the transfer of electrons...
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Introduction to Chemical Bonds01:01

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Chemical Bonds
The electrons of the outermost energy level determine the energetic stability of the atom and its tendency to form chemical bonds with other atoms. The innermost electron shell has a maximum capacity of two electrons, but the next two electron shells can each have a maximum of eight electrons. This is known as the octet rule, which states that, with the exception of the innermost shell, atoms are most stable energetically when they have eight electrons in their valence shell, the...
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Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
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区别的纽带

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概括
此摘要是机器生成的。

这项研究引入了一个新的描述符,Q,用于分析化学键类型. 基于能量分离,Q有效地分类各种键,从共价到离子和分散相互作用.

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科学领域:

  • 量子化学
  • 化学结合理论
  • 计算化学

背景情况:

  • 化学转换涉及每个电子的能量变化 (ΔE/n).
  • 这种能量变化可以分为平均电子结合能量 (Δχ̅) 和核排斥变化 (ΔVNN) 加上多电子相互作用 (Δω).
  • 之前的研究探讨了这种能量分离在化学结合中的后果.

研究的目的:

  • 扩大对各种二原子分子化学结合的能量分离的分析.
  • 引入一个新的描述符,Q,用于分类不同类型的化学键.
  • 研究Q与键能,以及Q与相关能之间的关系.

主要方法:

  • 化学转换的能量分成 Δχ̅, ΔVNN 和 Δω.
  • 基于 Δχ̅ 和 Δ(VNN + ω) / n 的缩放差异计算新的描述符 Q.
  • 绘制Q与键的能量,以分析键类型.

主要成果:

  • 描述器Q成功地分离和分类了广泛的结合类型,包括共价,极性,离子,金属,静电,电荷转移和分散相互作用.
  • 在这些不同的结合类别中,Q显示出与结合能量的明显相关性.
  • 在Q和债券的相关能量之间观察到有趣的关系.

结论:

  • 拟议的能量分区和描述符Q为理解和分类化学键类型提供了强大的框架.
  • Δχ̅与共价相关,而 Δω与电子转移相关.
  • 描述符Q为分析结合多样性及其与结合能量和电子相关性提供了有价值的工具.