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相关概念视频

Oxidation of Phenols to Quinones01:17

Oxidation of Phenols to Quinones

5.2K
In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox...
5.2K
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide02:44

Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

13.4K
Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
13.4K
Electron Transport Chain: Complex III and IV01:43

Electron Transport Chain: Complex III and IV

9.7K
During the electron transport chain, electrons from NADH and FADH2 are first transferred to complexes I and II, respectively. These two complexes then transfer the electrons to ubiquinol, which carries them further to complex III. Complex III passes the electrons across the intermembrane space to Cyt c, which carries them further to complex IV. Complex IV donates electrons to oxygen and reduces it to water. As electrons pass through complexes I, III, and IV, the energy released aids the pumping...
9.7K
Oxidation of Alcohols02:37

Oxidation of Alcohols

18.1K
In this lesson, the oxidation of alcohols is discussed in depth. The various reagents used for oxidation of primary and secondary alcohols are detailed, and their mechanism of action is provided.
The process of oxidation in a chemical reaction is observed in any of the three forms:
18.1K
Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids02:04

Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids

8.0K
Diols are compounds with two hydroxyl groups. In addition to syn dihydroxylation, diols can also be synthesized through the process of anti dihydroxylation. The process involves treating an alkene with a peroxycarboxylic acid to form an epoxide. Epoxides are highly strained three-membered rings with oxygen and two carbons occupying the corners of an equilateral triangle. This step is followed by ring-opening of the epoxide in the presence of an aqueous acid to give a trans diol.
8.0K
Anoxygenic Photosynthesis01:30

Anoxygenic Photosynthesis

1.6K
Anoxygenic photosynthesis is a phototrophic process that captures light energy to drive carbon fixation without producing molecular oxygen. Unlike oxygenic photosynthesis, which utilizes water as an electron donor and releases oxygen, anoxygenic phototrophs use alternative electron donors such as hydrogen sulfide (H₂S), elemental sulfur (S⁰), or thiosulfate (S₂O₃²⁻). This process is carried out by diverse groups of bacteria, including purple bacteria, green...
1.6K

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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

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通过Pd(0)-氨酸二氨酸复合物减少氧气

Kyle T Horak1, Theodor Agapie1

  • 1Division of Chemistry and Chemical Engineering, California Institute of Technology , 1200 East California Boulevard MC 127-72, Pasadena, California 91125, United States.

Journal of the American Chemical Society
|March 8, 2016
PubMed
概括

一个新的复合物与基连接物有效地减少各种小分子,包括氧气. 这种金属合反应突出了连接物

科学领域:

  • 有机金属化学
  • 协调化学

背景情况:

  • 新型配体的开发对于促进催化是至关重要的.
  • 在金属复合体中提供独特的反应途径.

研究的目的:

  • 合成和描述一种具有基部分的新型p-terphenyl diphosphine连接物.
  • 研究由此产生的金属复合物的反应性,特别是小分子.
  • 通过二坐标-化复合物来阐明二氧化降解的机制.

主要方法:

  • 一种含有基核的p-二联体的合成.
  • 与Ni(0) 和Pd(0) 前体发生金属化反应,形成金属复合物.
  • 通过单金属化和减少制备2坐标Pd(0)-化合物.
  • 用各种小分子进行反应性研究,包括O2,NO,N2O和有机氧化物.
  • 使用对照化合物和低温研究的机制研究.

主要成果:

  • 合成了一种含有基的新型二素配体.
  • 形成了伪四面体的Ni{0}和Pd{0}-子复合体.
  • 一个2坐标的Pd(0)-基复合体表现出对小分子的金属合反应性.
  • 这种复合物量减少了O2,NO,N2O和有机氧化物,产生了Pd(0) - 子产物.

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Expression and Purification of Nuclease-Free Oxygen Scavenger Protocatechuate 3,4-Dioxygenase
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  • 二氧化物还原过程通过一个eta(2) - peroxo中间体,然后是连接物氧化.
  • 结论:

    • 复合体中的基部分在小分子激活和减少中起着关键作用.
    • 双坐标Pd(0) - 胺复合物是各种基质的强有力的减少剂.
    • 二氧化激活是一种基于Pd的内部球体过程,基配体参与后续的还原步骤.