Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Network Covalent Solids02:18

Network Covalent Solids

16.5K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.5K
Covalent Bonding and Lewis Structures02:46

Covalent Bonding and Lewis Structures

67.4K
Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
67.4K
Covalent Bonds01:29

Covalent Bonds

167.7K
Overview
167.7K
Covalent Bonds01:08

Covalent Bonds

12.3K
Overview
When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
12.3K
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

31.6K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
31.6K
Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

2.0K
Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
2.0K

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

Covalent Organic Framework Photocatalysts: Decoding Linkage Chemistry in Hydrogen Peroxide Synthesis From Air and Water.

Angewandte Chemie (International ed. in English)·2026
Same author

HDAC3 in Alzheimer's Disease: established evidence, unresolved questions, and translational priorities.

Molecular biology reports·2026
Same author

Seven Models for Outer Surface-Only Functionalized Nanofluidic Systems.

ACS nano·2026
Same author

Topology-Engineered Three-Dimensional Porphyrin-Based Covalent Organic Frameworks for Photo- and Electrocatalysis.

Chemistry (Weinheim an der Bergstrasse, Germany)·2026
Same author

Acylhydrazone-Linked Covalent Organic Frameworks.

Journal of the American Chemical Society·2026
Same author

Single crystal covalent organic frameworks.

Chemical Society reviews·2026

相关实验视频

Updated: Mar 22, 2026

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
08:42

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

Published on: July 10, 2017

14.2K

高排放的共价有机框架

Sasanka Dalapati1, Enquan Jin2, Matthew Addicoat3

  • 1Field of Energy and Environment, School of Materials Science, Japan Advanced Institute of Science and Technology , 1-1 Asahidai, Nomi 923-1292, Japan.

Journal of the American Chemical Society
|April 26, 2016
PubMed
概括
此摘要是机器生成的。

研究人员使用聚合诱导排放 (AIE) 机制开发了高排放的共价有机框架 (COF),克服了聚合引起的火 (ACQ) 的限制. 这些AIE-COF显示出高量子产量和敏感的氨探测.

更多相关视频

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
05:26

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

Published on: February 10, 2023

4.0K
A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
10:13

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks

Published on: April 28, 2023

3.2K

相关实验视频

Last Updated: Mar 22, 2026

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
08:42

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

Published on: July 10, 2017

14.2K
Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
05:26

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

Published on: February 10, 2023

4.0K
A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
10:13

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks

Published on: April 28, 2023

3.2K

科学领域:

  • 材料科学
  • 超分子化学
  • 纳米技术

背景情况:

  • 协价有机框架 (COF) 通常遭受聚合引起的火 (ACQ),限制其发光特性.
  • 由于它们的分层结构中的 π-π 叠加,实现高发光的 COF 是一个重大挑战.

研究的目的:

  • 制定设计高排放COF的总体策略.
  • 通过引入聚合诱导排放 (AIE) 机制来克服COF中的ACQ的限制.

主要方法:

  • 将AIE活动单位集成到COF结构的顶部.
  • 具有周期性 π 堆叠柱状 AIE 阵列的晶体多孔 COF 的合成.
  • 光特性和氨感应能力的表征.

主要成果:

  • 通过集成的AIE单元成功设计和合成高排放的COF.
  • 在COF中,柱状AIE π阵列主导着发光,表现出异常的量子产量.
  • 通过使用AIE-COF来检测到低于ppm的高度敏感的氨.

结论:

  • 拟议的策略有效地克服了基于ACQ的COF发光的限制.
  • 这项工作为探索和开发高排放性COF材料开辟了新的途径.
  • 开发的AIE-COF显示出对敏感化学传感应用的希望.