通过电子-合-质子缓冲器介导的太阳能驱动的水氧化和脱生产
Leanne G Bloor1, Renata Solarska2,3, Krzysztof Bienkowski3
1WestCHEM School of Chemistry, University of Glasgow , University Avenue, Glasgow G12 8QQ, United Kingdom.
Journal of the American Chemical Society
|May 10, 2016
概括
这项研究引入了用于光电化学电池 (PEC) 的太阳能驱动水分解的电子合质缓冲器 (ECPB). 这种方法可以在不产生的情况下实现高效氧化演变,从而实现单独的高效生成.
科学领域:
- 可再生能源技术
- 摄影化学
- 电化学
背景情况:
- 太阳能到的光电化学电池 (PEC) 为可持续的H2燃料生产提供了一个有前途的途径.
- 传统的PEC会受到氧气和进化的反应的影响,从而限制了效率和气体纯度.
研究的目的:
- 开发一种新的方法来解开PEC中的氧和进化.
- 提高太阳能驱动的水分效率和气体选择性.
主要方法:
- 在光电化学电池中使用的氧化 (WO3) 光电极.
- 使用电子合质子缓冲器 (ECPB),特别是H3PMo12O40,以促进太阳能驱动的氧气进化.
- 通过电化学再氧化降解ECPB以产生.
主要成果:
- 在没有外部偏差的WO3光电极上达到超过1 mA cm(-2的太阳能驱动氧气演变速率.
- 证明在氧化过程中ECPB (H3PMo12O40) 降低为H5PMo12O40,防止PEC内产生H2.
- 在减少ECPB的电化学再氧化后获得H2的高法拉达效率.
结论:
- 开发的ECPB系统有效地解开了PEC中的氧和的演变.
- 这种方法克服了传统PEC的局限性,提高了太阳能燃料生产的效率和气体纯度.
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