使用单原子合金催化剂解决CO中毒问题
Jilei Liu1, Felicia R Lucci2, Ming Yang1
1Department of Chemical and Biological Engineering, Tufts University , 4 Colby Street, Medford, Massachusetts 02155, United States.
Journal of the American Chemical Society
|May 12, 2016
概括
单原子合金 (SAA) 催化剂通过削弱CO结合来提高对一氧化碳 (CO) 中毒的耐受性. 在化和燃料电池等关键工业反应中保持催化性能.
科学领域:
- 材料科学
- 催化剂
- 表面化学
背景情况:
- (Pt) 催化剂在工业和燃料电池中至关重要,但通过一氧化碳 (CO) 吸附而失活.
- 强大的CO与Pt表面结合是催化剂稳定性和寿命的主要限制.
研究的目的:
- 开发一种以为基础的催化剂,在保持催化活性的同时降低CO结合强度.
- 研究单原子合金 (SAA) 的策略,以提高催化剂的碳耐受性.
主要方法:
- 使用表面敏感性研究来量化不同组合的CO结合强度.
- 准备的-铜 (PtCu) 合金纳米粒子 (NP) 具有受控的组成.
- 使用乙烯化作为探针反应,以评估CO暴露下的催化剂性能.
主要成果:
- 一个PtCuSAA的Pt:Cu比为1:125显示显著减少了CO结合.
- 在H2激活过程中,SAA催化剂表现出极好的CO耐受性,这对于化和电氧化至关重要.
- 在SAANP上存在CO时,选择性化乙烯以乙烯进行,没有活动损失.
结论:
- 通过减弱二氧化碳吸附,SAA策略有效地减轻催化剂中的二氧化碳中毒.
- PtCu SAA催化剂为需要高CO容忍度的应用提供了有前途的解决方案,包括燃料电池和工业化.
- 这种方法对提高对CO抑制敏感的各种化学过程中的催化剂稳定性具有广泛的影响.
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