古老的微石暗示了富含氧气的古老的上层大气层
Andrew G Tomkins1, Lara Bowlt1, Matthew Genge2,3
1School of Earth, Atmosphere and Environment, Monash University, Melbourne, Victoria 3800, Australia.
Nature
|May 13, 2016
概括
早期地球的上层大气层可能有类似于今天的氧气水平,挑战了以前的假设. 化石微流星表明高氧度存在于27亿年前,与较低大气条件不同.
科学领域:
- 地质化学
- 古气候学
- 星球科学
背景情况:
- 在24亿年前的大氧化事件发生之前,地球大气层的氧气 (O2) 水平被认为非常低 (<0.001%).
- 之前的研究集中在下层大气组成上,缺乏分析Archaean上层大气的方法.
- 化石微石为上层大气条件提供了一个新的替代品.
研究的目的:
- 通过使用化石微流星来调查古老的上层大气氧度.
- 为了确定上层大气中的氧气水平是否与上层大气中的氧气水平有显著差异.
主要方法:
- 在澳大利亚皮尔巴拉地区从27亿年前的石灰岩中提取化石微隕石.
- 从微流星形成的宇宙球体内铁 (FeNi) 金属的氧化状态的分析.
- 在不同的大气条件下模拟微石氧化过程.
主要成果:
- 微石形成了磁铁 (Fe3O4) 和维斯 (FeO) +金属的球体,表明氧化发生在高海拔 (75-90公里) 的化过程中.
- 氧化模式表明,古老的上层大气氧度与今天的水平相似.
- 氧气与一氧化碳的比率足以允许氧化,不受一氧化碳抑制的影响.
结论:
- 古代高层大气中的氧气含量可能远高于从低层大气数据中推断出的.
- 在海底石中异常的硫同位素标志表明上层和下层之间的大气混合有限.
- 这意味着有层次的大气层可能富含氧气的上层和无氧的表面条件.
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