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Updated: Mar 21, 2026

Preparation and Use of Samarium Diiodide SmI2 in Organic Synthesis: The Mechanistic Role of HMPA and NiII Salts in the Samarium Barbier Reaction
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Preparation and Use of Samarium Diiodide SmI2 in Organic Synthesis: The Mechanistic Role of HMPA and NiII Salts in the Samarium Barbier Reaction

Published on: February 4, 2013

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通过具有Fe- [5'-C]-脱氧腺键的有机金属中间体进行激进SAM催化

Masaki Horitani1, Krista Shisler2, William E Broderick2

  • 1Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.

Science (New York, N.Y.)
|May 14, 2016
PubMed
概括

研究人员检测到激素S- 腺甲 (SAM) 酶反应中的一个关键中间体. 这一发现揭示了一个新的有机金属中心, 进步了我们对这些重要的生物催化剂的理解.

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