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KOtBu:一种电子转移反应的特权反应剂?

Joshua P Barham1,2, Graeme Coulthard1, Katie J Emery1

  • 1WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde , 295 Cathedral Street, Glasgow G1 1XL, U.K.

Journal of the American Chemical Society
|May 17, 2016
PubMed
概括

三氧化物 (KOtBu) 通常通过在现场形成有机电子捐赠者,而不是直接捐赠电子来促进单个电子转移反应. 直接从KOtBu转移电子只能通过特定的电子受体,如碳四化物 (CBr4).

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