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The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
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脱水-迪尔斯-阿尔德反应的扭曲控制反应和分子动力学

Peiyuan Yu1, Zhongyue Yang1, Yong Liang1

  • 1Department of Chemistry and Biochemistry, University of California , Los Angeles, California 90095, United States.

Journal of the American Chemical Society
|June 12, 2016
PubMed
概括

密度函数理论研究表明,扭曲能量控制了脱水-迪尔斯-阿尔德 (DDA) 反应活性. 对于六度--阿尔德 (HDDA) 反应,由于显著的扭曲能量需求,协调和阶段性机制具有竞争力.

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