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Updated: Mar 19, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
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Published on: December 4, 2017

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通过含有贵金属代替铁的人工血红蛋白进行非生物催化

Hanna M Key1,2, Paweł Dydio1,2, Douglas S Clark3,4

  • 1Department of Chemistry, University of California, Berkeley, California 94720, USA.

Nature
|June 15, 2016
PubMed
概括

研究人员通过用像这样的贵金属替代蛋白质中的铁,制造出新的人工酶. 这些工程金属酶催化新的化学反应,包括C-H键功能化和选择性循环化,扩大了生物催化的可能性.

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Enzymes require additional components for proper function. There are two such classes of molecules: cofactors and coenzymes. Cofactors are metallic ions and coenzymes are non-protein organic molecules. Both of these types of helper molecule can be tightly bound to the enzyme or bound only when the substrate binds.
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