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相关概念视频

Ferromagnetism01:31

Ferromagnetism

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Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
3.4K
Types of Semiconductors01:20

Types of Semiconductors

1.7K
Intrinsic semiconductors are highly pure materials with no impurities. At absolute zero, these semiconductors behave as perfect insulators because all the valence electrons are bound, and the conduction band is empty, disallowing electrical conduction. The Fermi level is a concept used to describe the probability of occupancy of energy levels by electrons at thermal equilibrium. In intrinsic semiconductors, the Fermi level is positioned at the midpoint of the energy gap at absolute zero. When...
1.7K
Dielectric Polarization in a Capacitor01:31

Dielectric Polarization in a Capacitor

6.4K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
6.4K
Electrostatic Boundary Conditions in Dielectrics01:27

Electrostatic Boundary Conditions in Dielectrics

2.0K
When an electric field passes from one homogeneous medium to another, crossing the boundary between the two mediums imparts a discontinuity in the electric field. This results in electrostatic boundary conditions that depend on the type of mediums the field propagates through.
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's permittivity....
2.0K
Valence Bond Theory02:42

Valence Bond Theory

11.5K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
11.5K
Theory of Metallic Conduction01:17

Theory of Metallic Conduction

1.9K
The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
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Measuring Magnetically-Tuned Ferroelectric Polarization in Liquid Crystals
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从第一个原则出发的内在铁电切换

Shi Liu1, Ilya Grinberg2,3, Andrew M Rappe2

  • 1Geophysical Laboratory, Carnegie Institution for Science, Washington DC 20015, USA.

Nature
|June 17, 2016
PubMed
概括

铁电材料的域壁运动是极化切换的关键. 这项研究提出了一个普遍的模型,从第一原理预测材料特性,与更好的材料设计的实验结果保持一致.

科学领域:

  • 凝聚物质物理学
  • 材料科学

背景情况:

  • 域墙影响铁电特性,如介电,压电和火电反应.
  • 域壁运动对于极化切换至关重要,在铁电材料中观察到歇斯底里循环.
  • 目前的模型通常依赖于缺陷驱动的固定,导致依赖样本的行为并阻碍理论预测.

研究的目的:

  • 为铁电领域的域壁动力学开发一种通用分析模型.
  • 连接微观的,第一原则的计算与宏观的,有限的温度特性.
  • 为了能够准确地预测设备设计和发现的铁电材料特性.

主要方法:

  • 在酸 (PbTiO3) 中对90°域壁进行分子动力学模拟.
  • 基于核和生长的分析模型的开发.
  • 预测歇斯底里循环和强制场的温度和频率依赖的第一原理计算.

主要成果:

  • 构建了一个简单的,通用的域墙动态模型,适用于各种铁电.
  • 描述了域壁速度的内在温度和场所依赖性,显示非线性爬行和分离区域.
  • 预测的强制场与陶和薄膜的实验数据有很好的一致性.

结论:

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  • 铁电切换在很大程度上是由内在的域壁运动控制的,即使没有缺陷.
  • 开发的模型为预测和优化铁电材料性能提供了有效的框架.
  • 这项工作弥合了理论计算和实验观测之间的差距,促进了材料的发现.