在固体上切换液体的粘合和粘附
Stijn F L Mertens1,2, Adrian Hemmi3, Stefan Muff3
1Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium.
Nature
|July 1, 2016
概括
研究人员研究了六角化和在液滴中的粘合和粘合. 他们发现,这些力量可以通过电化学潜能进行可逆切换,从而提供了对微型设备设计的见解.
科学领域:
- 材料科学 材料科学 材料科学
- 表面科学是一门学科.
- 部落学 (tribology) 是一个学科.
背景情况:
- 粘合和粘合对于机动和微型设备的功能至关重要.
- 了解粘附,粘结和滑动摩擦之间的关系往往是经验性的.
- 更好的理解可以推进微和纳米电机系统 (MEMS/NEMS) 设计.
研究的目的:
- 为了研究固体-液体界面上的粘合和粘附之间的关系.
- 探索一种新的可切换表面系统,用于控制粘合和粘合.
- 为了更深入地了解粘附和摩擦机制.
主要方法:
- 在六角化 (h-BN) 单层上的动态接触角测量. 在上.
- 研究两个不同的接口状态:波纹 (没有间隔) 和平面 (间隔诱导).
- 利用电化学潜能可逆控制间隔和表面状态.
主要成果:
- 通过控制间,通过控制间,证明了粘合和粘合的可逆切换.
- 观察到的粘附变化归因于双极环侧面电场的变化,而不是表面粗度.
- h-BN/Rh系统具有很高的稳定性和可切换的表面性能.
结论:
- 在h-BN/Rh接口上的粘附和粘附可以通过电化学控制间隔进行切换.
- 观察到的粘附变化与电场变化有关,提供了超越温泽尔模型的机制.
- 这种稳定,可切换的表面系统在粘附,摩擦和滑研究中具有潜在的应用.
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