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相关概念视频

Preparation of Alcohols via Addition Reactions02:15

Preparation of Alcohols via Addition Reactions

8.1K
Overview
The acid-catalyzed addition of water to the double bond of alkenes is a large-scale industrial method used to synthesize low-molecular-weight alcohols. An acidic atmosphere is required to allow the hydrogen in the water molecule to act as an electrophile and attack the double bond in an alkene. The addition of a proton to the double bond creates a carbocation intermediate. The proton preferentially bonds to the less substituted end of the double bond to create a more stable carbocation...
8.1K
Dehydration of Aldols to Enals: Base-Catalyzed Aldol Condensation01:14

Dehydration of Aldols to Enals: Base-Catalyzed Aldol Condensation

7.4K
This lesson delves into the aldol condensation catalyzed by bases, where aldols undergo dehydration to enals. As shown in Figure 1, the β-hydroxy aldehyde formed in a base-catalyzed aldol addition reaction dehydrates on heating to yield an unsaturated carbonyl product, which is commonly referred to as an enal.
7.4K
C–C Bond Formation: Aldol Condensation Overview01:10

C–C Bond Formation: Aldol Condensation Overview

17.6K
Aldol condensation is an important route in synthetic organic chemistry used to generate a new carbon–carbon bond under basic or acidic conditions. The aldol condensation reaction presented in Figure 1 constitutes an aldol addition reaction followed by the dehydration process.
17.6K
Aldehydes and Ketones with Alcohols: Hemiacetal Formation01:19

Aldehydes and Ketones with Alcohols: Hemiacetal Formation

10.5K
Similar to water, alcohols can add to the carbonyl carbon of the aldehydes and ketones. The addition of one molecule of alcohol to the carbonyl compound forms the hemiacetal or half acetal. As depicted below, in a hemiacetal, the carbon is directly linked to an OH and OR group.
10.5K
Ethers from Alcohols: Alcohol Dehydration and Williamson Ether Synthesis02:29

Ethers from Alcohols: Alcohol Dehydration and Williamson Ether Synthesis

13.3K
Overview
Ethers can be prepared from organic compounds by various methods. Some of them are discussed below,
Preparation of Ethers by Alcohol Dehydration
In this method, in the presence of protic acids, alcohol dehydrates to produce alkenes and ethers under different conditions. For example, in the presence of sulphuric acid, dehydration of ethanol at 413 K yields ethoxyethane, whereas it yields ethene at 443 K.
13.3K
Physical Properties of Alcohols and Phenols02:32

Physical Properties of Alcohols and Phenols

17.2K
Alcohols are organic compounds in which a hydroxy group is attached to a saturated carbon. Phenols are a class of alcohols containing a hydroxy group attached to an aromatic ring. The physical properties of the alcohols and phenols are influenced by hydrogen bonding due to the oxygen–hydrogen dipole in the hydroxy functional group and dispersion forces between alkyl or aryl regions of alcohol and phenol molecules.
Alcohols possess a higher boiling point than aliphatic hydrocarbons of similar...
17.2K

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Rapid One-step Enzymatic Synthesis and All-aqueous Purification of Trehalose Analogues
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非天然糖醇的计算设计以增加热储存密度:超出现有的有机相变材料

Taichi Inagaki1,2, Toyokazu Ishida1,2

  • 1Research Center for Computational Design of Advanced Functional Materials (CD-FMat), National Institute of Advanced Industrial Science and Technology (AIST) , Tsukuba Central 2, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568, Japan.

Journal of the American Chemical Society
|August 10, 2016
PubMed
概括
此摘要是机器生成的。

研究人员通过计算设计出新的糖醇来增强热能储存. 这些材料的热储密度可能比目前的有机相变材料 (PCM) 高得多.

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科学领域:

  • 材料科学
  • 计算化学
  • 能量储存

背景情况:

  • 有效的热能管理对于节能社会至关重要,需要能够储存大量热能的材料.
  • 糖醇是相变材料 (PCM) 的有希望的候选物,因为它们的热储密度很高.

研究的目的:

  • 通过计算设计具有增强热储存性能的新型非天然糖醇.
  • 预测这些设计的分子的热储密度,作为开发高性能PCM的一步.

主要方法:

  • 在非天然糖醇的分子设计中,遵循特定的指导方针 (线性骨干,分离的OH组,甚至是碳原子).
  • 使用随机搜索和第一原则计算预测晶体结构.
  • 分子模拟以确定热储密度.

主要成果:

  • 设计的非天然糖醇具有大约450-500kJ/kg的预测热储密度.
  • 这远高于已知的有机PCM的典型最大值约350kJ/kg.
  • 分子扭曲和范德瓦尔斯能量被确定为增加H结合晶体的热储密度的重要因素.

结论:

  • 通过计算设计的非天然糖醇显示出优越的热能储存潜力.
  • 异构体选择对于优化这些材料的热储密度至关重要.
  • 这项研究强调了在高性能PCM中考虑静电以外的多种能源因素的重要性.