素结合促进了更高的染料敏感的太阳能电池光伏
Sarah J C Simon1, Fraser G L Parlane1, Wesley B Swords2
1Departments of Chemistry and Chemical & Biological Engineering, The University of British Columbia , 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada.
Journal of the American Chemical Society
|August 13, 2016
概括
在染料敏感太阳能电池 (DSSC) 中的素结合增强光伏. 染料中较重的素可以提高染料的再生率,提高细胞的整体性能和开放电路电压 (VOC).
科学领域:
- 材料科学
- 太阳能发电
- 电化学
背景情况:
- 染料敏感太阳能电池 (DSSC) 是一个有前途的光伏技术.
- 优化染料再生和光伏对于DSSC的效率至关重要.
- 素结合是光伏材料中未被充分探索的相互作用.
研究的目的:
- 研究DSSC中素结合相互作用的作用.
- 确定基替代剂对染料再生率 (kreg) 的影响.
- 将染料再生动力与开放电路电压 (VOC) 的增强相关联.
主要方法:
- 用不同的素替代剂合成和表征三胺基染料.
- 使用这些定制染料和核友电解质 (I(-) 制造DSSC.
- 测量染料再生速率常数 (kreg) 和开放电路电压 (VOC).
主要成果:
- 使用较重的素替代剂的染料显示出显著更大的染料再生速率常数 (kreg).
- DSSC的开放电路电压与观察到的克雷格值直接相关.
- 在光氧化染料和电解质之间观察到素结合相互作用的直接证据.
结论:
- DSSC光电显然对染料再生速度 (kreg) 有敏感性.
- 染料和电解质之间的素结合相互作用可以有效地提高DSSC的性能.
- 战略性纳入素为DSSC提供了改善染料再生和光电的途径.
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