通过随机共聚合物方法实现高效太阳能电池的实用性
Chunhui Duan1, Ke Gao2, Jacobus J van Franeker1,3
1Molecular Materials and Nanosystems, Institute for Complex Molecular Systems, Eindhoven University of Technology , P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Journal of the American Chemical Society
|August 13, 2016
概括
研究人员通过随机共聚化合成了有机太阳能电池的先进半导体共聚物. 这些材料达到8.0%的高功率转换效率 (PCE),性能优于原始聚合物,并显示出最小的批量变化.
科学领域:
- 材料科学
- 有机电子
- 太阳能发电
背景情况:
- 有机太阳能电池 (OSC) 需要高效的半导体材料来提高性能.
- 开发具有定制电子特性的新型共聚物对于推进OSC技术至关重要.
研究的目的:
- 探索随机共聚化作为合成高性能半导体共聚物的策略.
- 研究单体组合对有机太阳能电池性能和效率的影响.
主要方法:
- 半导体共聚物的合成通过[1,2-b:4,5-b']二甲和5,6-二[2,1,3]二甲基单体的随机共聚.
- 有机太阳能电池设备中的共聚物特性和性能.
- 使用常规溶剂和非化溶剂制造活性层.
主要成果:
- 随机共聚物实现了约8.0%的功率转换效率 (PCE).
- 与它们的二元母聚合物相比,合成的共聚物呈现出更高的PCE.
- 在不同配合聚合物组合中观察到最小的批量变化.
- 即使在室温下从非化溶剂处理活性层时,也保持了高的PCE.
结论:
- 电子丰富和缺乏电子的单体的随机共聚化是创建高性能半导体材料的成功策略.
- 开发的共聚物为高效和可扩展的有机太阳能电池制造提供了有希望的途径.
- 在室温下使用非化溶剂的加工表明了环保和成本效益的制造潜力.
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