通过氧化合在层状Y2O2Bi中的单原子Bi2-) 方形网出现了二维超导性
Ryosuke Sei1,2, Suguru Kitani3, Tomoteru Fukumura2
1Department of Chemistry, Graduate School of Science, The University of Tokyo , Tokyo 113-0033, Japan.
Journal of the American Chemical Society
|August 20, 2016
概括
研究人员在2K的Y2O2Bi中发现了二维超导性.这种新的超导性出现在含氧的化合物中,表明元素的结合是寻找超导体的新途径.
科学领域:
- 材料科学
- 凝聚物质物理学
- 固态化学
背景情况:
- 像酸盐和铁基化合物这样的多层超导体对于科学发现至关重要.
- 具有过渡金属的近二维层是超导性的关键,通常通过价离子替代实现.
- 这些层结构中的载体合是实现超导的首要机制.
研究的目的:
- 在一个新的氧化物,Y2O2Bi中发现二维超导.
- 调查氧气结合和结构修改对Y2O2Bi超导性的作用.
- 通过将元素纳入间位点来探索发现超导体的新方法.
主要方法:
- 合成ThCr2Si2型层氧化物Y2O2Bi.
- 将氧气控制到Y2O2Bi结构中.
- 研究结构变化,特别是互联网距离的扩大.
- 在低温 (2K) 上检测超导电阻的电阻测量.
主要成果:
- 在Y2O2Bi中发现二维超导.
- 只有在含有氧的样本中观察到超导,而不是原始的Y2O2Bi.
- 氧气的结合导致了Y2O2Bi结构的网络间距离扩大.
- 导电的单原子Bi(2-) 方网可能与外来超导有关.
结论:
- 将元素纳入间位是发现新型超导体的可行替代策略.
- 这些发现强调了结构修改的重要性,例如网络间距离,在实现超导性方面.
- 这项研究为探索不同层次材料的超导性开辟了新的途径.
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