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在不同流体的存在下,地质石化胺酸框架化合物的高压化学

Junhyuck Im1, Narae Yim2, Jaheon Kim2

  • 1Department of Earth System Sciences, Yonsei University , Seoul 03722, Korea.

Journal of the American Chemical Society
|August 31, 2016
PubMed
概括

焦化物伊米达酸框架化合物ZIF-8经历了压力诱导的结构变化. 根据压力传导介质,ZIF-8的单元体积反应不同,在酒精中呈扩张,在水中呈收缩.

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Basicity of Heterocyclic Aromatic Amines01:25

Basicity of Heterocyclic Aromatic Amines

Heterocyclic amines, where the N atom is a part of an alicyclic system, are similar in basicity to alkylamines. Interestingly, the heterocyclic amine having a nitrogen atom as part of an aromatic ring has much less basicity than its corresponding alicyclic counterpart. For this reason, as presented in Figure 1, piperidine (pKb = 2.8) is significantly more basic than pyridine (pKb = 8.8).
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