作为离散能量储存载体的氧化活性体
Elena C Montoto1,2, Gavvalapalli Nagarjuna1,2, Jingshu Hui1,3
1Joint Center for Energy Storage Research , United States.
Journal of the American Chemical Society
|September 16, 2016
概括
研究人员开发了用于储能的新型氧化还原活性合物 (RAC). 这些模块化聚合物球在电池和流系统中提供稳定,高效的循环.
科学领域:
- 材料科学
- 电化学
- 聚合物化学
背景情况:
- 先进的电池材料对于储存可再生能源至关重要.
- 现有的有机材料面临着跨度和稳定性等挑战.
- 需要与各种电池设计兼容的多功能模块化材料.
研究的目的:
- 引入一个新的材料类别:氧化还原活性合物 (RAC).
- 证明RAC的模块化和稳定性
- 探索RAC在储能应用中的潜力.
主要方法:
- 控制直径 (80-800 nm) 的交联聚合物球 (RAC) 的合成.
- 作为单个粒子,膜和分散物的RAC的电化学表征.
- 在大量电解中测试基于viologen的RAC,并在非水性氧化还原流电池中测试ferrocene/viologen的RAC.
主要成果:
- 基于Viologen的RAC在50个循环中实现了99%的容量保留和99 ± 1%的库伦比效率.
- 通过长距离的粒子内部电荷转移证明了有效的循环.
- 一个非水性氧化还原流电池的成功运行,使用铁素和维奥RAC与尺寸选择分离器.
结论:
- 反氧化活性合物为小分子有机电池材料提供了多功能和稳定的替代品.
- RAC的模块化设计和体性质使得新的储能解决方案成为可能.
- RAC为下一代可再生能源储能系统提供了一个有前途的平台.
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