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Updated: Mar 14, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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基于过渡金属复合和π电子捐赠-接受相互作用的可切换混合体

David B Amabilino1, Christiane O Dietrich-Buchecker1, Aude Livoreil1

  • 1Contribution from the Laboratoire de Chimie Organo-Minérale, URA 422 du CNRS, Institut Le Bel, Université Louis Pasteur, 4, rue Blaise Pascal, 67070 Strasbourg, France, and The School of Chemistry, The University of Birmingham, Edgbaston, Birmingham B15 2TT, U.K.

Journal of the American Chemical Society
|October 8, 2016
PubMed
概括

一种新型的双模 [2] - 连锁可以在金属复合体和π电子捐赠-接受模式之间切换. 这种由阴离子添加/去除引发的结构重组可以通过核磁共振和电子光谱观察.

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