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相关概念视频

Solid–Solid Solutions01:24

Solid–Solid Solutions

52
The temperature-composition phase diagram of two solids, A and B, which are immiscible in the solid phase but form miscible liquids, shows that when the temperature is low, these two exist as separate, pure solids (A and B). As the temperature increases, they transition into a single-phase liquid solution where A and B coexist. Moving from point a1 to a2 in the phase diagram, the composition changes such that solid B begins to separate from the solution, enriching the remaining liquid with A.
52
Recrystallization: Solid–Solution Equilibria01:10

Recrystallization: Solid–Solution Equilibria

4.2K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.4K
Liquid–Solid Solutions01:29

Liquid–Solid Solutions

45
The process of a solid dissolving in a liquid to form a solution is governed by the solubility limit, which is the maximum amount of the solid substance, or solute, that can be dissolved in a specific volume of the liquid or solvent. As the solute dissolves, it reaches a point where no more solute can be dissolved at a given temperature - this is known as the saturation point. However, if further solute is added and it manages to dissolve, the solution becomes supersaturated. Supersaturated...
45

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相关实验视频

Updated: Mar 14, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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超硬的/二氧化固体溶液

Andrew T Lech, Christopher L Turner, Jialin Lei

  • 1Department of Mechanical and Nuclear Engineering, Virginia Commonwealth University , Richmond, Virginia 23284, United States.

Journal of the American Chemical Society
|October 11, 2016
PubMed
概括
此摘要是机器生成的。

二氧化 (ReB2) 保持超硬,即使高达48%的. 这一发现扩大了超硬ReB2结构材料在先进应用中的潜力.

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Negative Additive Manufacturing of Complex Shaped Boron Carbides
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科学领域:

  • 材料科学
  • 固态化学
  • 晶体学

背景情况:

  • 二 (ReB2) 是一种具有独特波层结构的超硬金属化合物.
  • 二 (WB2) 呈现出混合结构,并非超硬,表明结构对超硬的敏感性.

研究的目的:

  • 研究二固体溶液的结构稳定性和机械性能.
  • 在保持超硬度的同时确定ReB2结构中替代的极限.

主要方法:

  • 二固体溶液的合成
  • 粉末X射线和中子衍射用于结构分析.
  • 用于机械性能评估的微型和纳米级硬度测试.

主要成果:

  • ReB2类型的结构保持在含量高达近50%的原子.
  • 格子参数随着含量线性增加.
  • 所有组合 (0-48 原子 % W) 都表现出超硬度,48 原子 % 固体溶液的体积模量与纯 ReB2相当.

结论:

  • 二固体溶液在广泛的组成范围内保持超硬度.
  • ReB2结构类型与超硬性相关.
  • 需要对相关的固体溶液和三元化合物进行进一步的研究.