与石墨烯发生摩擦接触的不断变化的质量
Suzhi Li1,2,3, Qunyang Li4,5, Robert W Carpick6
1State Key Laboratory for Mechanical Behavior of Materials and Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049, China.
Nature
|November 25, 2016
概括
随着时间的推移,由于它们的灵活性,薄石墨烯层中的摩擦会增加,使原子能够更好地对齐和粘附. 这种对理解灵活接口至关重要的效果随着层次的增加而减弱.
科学领域:
- 部落学
- 材料科学
- 纳米技术
背景情况:
- 像石墨这样的状材料作为干滑剂.
- 单层石墨烯比多层石墨烯具有更高的时间依赖摩擦,这一现象尚未得到充分解释.
- 接触面积数量传统上与摩擦有关,但接触质量正在成为关键因素.
研究的目的:
- 阐明在石墨烯中观察到的依赖层的短暂摩擦强化的机制.
- 通过计算重现石墨烯独特摩擦行为的实验结果.
- 调查接触质量的作用,超出接触区域,在表面摩擦.
主要方法:
- 用原子模拟来模拟石墨烯的摩擦.
- 原子力分析用于检查静态摩擦的演变.
- 研究了石墨烯灵活性和基板粘附性的影响.
主要成果:
- 模拟成功地重现了对石墨烯层依赖摩擦和瞬时增强的实验观测.
- 较薄,较少受约束的石墨烯层由于原子配置的调整和增强的固定而增加了静态摩擦.
- 接触质量,包括局部原子固定和相称性,在滑动过程中发生变化,并显著影响摩擦.
结论:
- 由于石墨烯的灵活性,不断变化的接触质量对于解释二维材料的时间依赖摩擦至关重要.
- 暂时的摩擦强化是原子层重排的结果,并固定在较薄的石墨烯层中.
- 摩擦性能可以通过诸如纹的因素来调整,这突显了接口配置的重要性.
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