纳米级内在化物分离决定了混合阴离子/混合化物矿太阳能电池的高效率
Paul Gratia1, Giulia Grancini1, Jean-Nicolas Audinot2
1Group for Molecular Engineering of Functional Materials (GMF), Institute of Chemical Sciences and Engineering, Swiss Federal Institute of Technology , CH-1951 Sion, Switzerland.
Journal of the American Chemical Society
|December 15, 2016
概括
混合矿太阳能电池显示组成分离成富含的纳米领域. 这种矿的自我组织会影响膜的同质性和光学特性,这对设备的性能至关重要.
科学领域:
- 材料科学
- 可再生能源
- 纳米技术
背景情况:
- 混合的阴离子/化物矿,如 (FAPbI3) 0.85(MAPbBr3) 0.15,是高效的矿太阳能电池的关键.
- 了解矿的自我组织和元素分布对于优化设备性能至关重要.
研究的目的:
- 在混合矿薄膜中绘制纳米级电荷载体和元素分布.
- 研究构成工程对矿薄膜同质性和光学性能的影响.
主要方法:
- 使用了一种新的离子显微镜与二次离子质谱学 (HIM-SIMS) 相结合.
- 使用凯尔文探针力显微镜 (KPFM) 进行纳米分析.
- 分析了20%效率的太阳能电池中的混合矿膜.
主要成果:
- 证明混合矿薄膜的内在分离为含丰富的纳米域 (高达几百纳米).
- 由于纳米领域分离而导致膜均性的破坏.
- 在微米尺度上观察到的光学特性变化,与组成不均有关.
结论:
- 提供了对纳米级矿组成和自我组织的前所未有的洞察力.
- 突出了纳米级元素分布在混合矿薄膜中的关键作用.
- 强调需要控制矿的自我组织,以提高太阳能电池的效率.
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