一个染料敏感的光电化学双电池,用于光驱动的从水中生产气
Benjamin D Sherman1, Matthew V Sheridan1, Kyung-Ryang Wee1
1Department of Chemistry, University of North Carolina at Chapel Hill , Chapel Hill, North Carolina 27599, United States.
Journal of the American Chemical Society
|December 16, 2016
概括
这项研究开发了一种使用染料敏感的光电化学电池 (DSPEC) 和染料敏感的太阳能电池 (DSC) 的双重光电化学分水系统. 最好的配置显示了仅使用太阳光照明从水中产生.
科学领域:
- 材料科学
- 可再生能源
- 摄影化学
背景情况:
- 通过使用多个吸光器,并联光电化学分水器提供比单个吸光器系统更高的效率.
- 对于可再生能源技术而言,从水分化中有效生产气至关重要.
研究的目的:
- 开发和评估一个双重光电化学分水系统.
- 研究染料敏感的光电化学电池 (DSPEC) 与染料敏感的太阳能电池 (DSC) 的性能.
主要方法:
- 一个由DSPEC与基于的水氧化催化剂和DSC组成的双重系统的制造.
- 测试两个DSC变异:一个用N719染料和化物/三化物介质,另一个用D35染料和 (III/II) 双介质.
- 通过模拟太阳照明来评估水中的产量.
主要成果:
- 使用DSPEC和D35/cobalt (III/II) 双DSC的双组配置表现出最高的性能.
- 从水 (H2O) 中有效地产生 (H2),仅由模拟太阳光提供动力.
结论:
- 配对染料敏感系统对于光电化学水分是有效的.
- 开发的DSPEC-DSC合装置显示了太阳能驱动的燃料生产的前景.
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