双轴应力PtPb/Pt核心/外纳米板可促进氧降解催化
Lingzheng Bu1, Nan Zhang1, Shaojun Guo2,3,4
1College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Jiangsu 215123, China.
概括
具有拉伸性菌株的/纳米板显著提高了氧降解反应活性. 这些耐用的催化剂在5万个循环中表现出极好的性能和稳定性.
科学领域:
- 材料科学
- 电化学
- 催化剂
背景情况:
- 压缩表面应变增强了核心/外M/ (Pt) 催化剂的氧降解反应 (ORR) 活性.
- 优化ORR活动对于燃料电池等电化学应用至关重要.
研究的目的:
- 开发和描述新的-/ (PtPb/Pt) 核心/外纳米板催化剂.
- 研究双轴应变对ORR活性和催化剂稳定性的影响.
主要方法:
- 合成PtPb/Pt核心/外纳米板.
- 对ORR活性 (特异性和质量活性) 的电化学表征.
- 用密度函数理论 (DFT) 计算来分析表面应变和粘合.
主要成果:
- 在0.9V与RHE相比,PtPb/Pt纳米板具有较高的ORR特异性活性 (7.8mA/cm2) 和质量活性 (4.3A/mg Pt).
- DFT计算显示Pt (110) 面上的拉伸力优化了Pt-O键强度.
- 催化剂表现出特殊的稳定性,可以承受5万个电压周期,没有显著的活性衰变或结构变化.
结论:
- 具有拉伸性菌株的PtPb/Pt核心/外纳米板是非常有效的ORR催化剂.
- 金属间核心和均的Pt外有助于提高催化剂的耐用性.
- 这些发现为开发先进的电催化剂提供了有前途的途径.
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