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Updated: Jun 14, 2026

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在微孔有机柱状酸盐中通过冷旋转动力学打开恒定体积

Kilian Bärwinkel1, Markus M Herling2, Martin Rieß2

  • 1Inorganic Chemistry III, University of Bayreuth , Universitätsstraße 30, 95440 Bayreuth, Germany.

Journal of the American Chemical Society
|December 20, 2016
PubMed
概括

微孔有机柱状酸盐 (MOPS) 通过调整柱状动力学来选择性地将二氧化碳从乙烯中分离出来. 这种新的门打开机制避免了框架压力和体积变化,与传统方法不同.

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Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
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Membrane bending can happen due to intrinsic changes in lipid composition or extrinsic association with different proteins. The proteins involved...