室温 磁性订制的极性冠状体 GaFeO3显示磁电合
Hongjun Niu1, Michael J Pitcher1, Alex J Corkett1
1Department of Chemistry, University of Liverpool , Crown Street, Liverpool L69 7ZD, United Kingdom.
Journal of the American Chemical Society
|December 27, 2016
概括
研究人员合成了一种新的多铁物质 - - 铁氧化 (GaFeO3),具有极性冠状体结构. 这种材料在室温下表现出弱铁磁性和磁电合,为新型多铁子装置铺平了道路.
科学领域:
- 材料科学
- 固态物理
- 晶体学
背景情况:
- 极地冠石结构为室温多铁材料提供了潜力.
- 将极性阴离子排序与磁性排序相结合是多铁体的关键.
研究的目的:
- 合成和表征一个极性高氧化铁 (GaFeO3).
- 调查它的极性和磁性属性的起源.
- 为了证明磁电合对潜在的设备应用.
主要方法:
- 高压,高温合成路径.
- 用中子,X射线和电子衍射进行结构分析.
- 在现场中子衍射观察相位形成.
- 密度函数理论 (DFT) 对排序行为进行计算.
- 磁化和磁电合测量
主要成果:
- 已经成功合成了GaFeO3的极性冠状体.
- 极性证实来自部分LiNbO3类型的阳离子排序.
- 观察到类似Fe2O3的磁性排序,持续到408K.
- 证明了0.057ps/m的线性磁电合系数.
结论:
- 极地金刚石 GaFeO3 是一个有前途的室温多铁材料.
- 阳离子排序对于实现极性至关重要,并且受到配置的影响.
- 证明的磁电合是多铁/磁电装置应用的先决条件.
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