电化学捕获和释放二氧化碳使用二硫化物-二氧化碳还氧化循环
Poonam Singh1, Joseph H Rheinhardt1, Jarred Z Olson2
1School of Molecular Sciences, Arizona State University , Tempe, Arizona 85281, United States.
Journal of the American Chemical Society
|January 5, 2017
概括
一个新的电化学循环使用酸来捕获和释放二氧化碳 (CO2). 这种基于硫的方法为二氧化碳捕获提供了新的途径,与传统的氨基策略不同.
科学领域:
- 电化学
- 绿色化学
- 材料科学
背景情况:
- 捕获二氧化碳对于缓解气候变化至关重要.
- 现有的二氧化碳捕获技术,如氨基洗,面临能源效率和降解的挑战.
- 开发替代捕获剂和电化学循环是一个活跃的研究领域.
研究的目的:
- 引入和描述一个新的二氧化碳捕获和释放的电化学循环.
- 调查使用酸作为二氧化碳捕获剂.
- 探索硫结合的硫碳酸盐的电化学行为.
主要方法:
- 从二硫化物产生酸的电化学生成.
- 甲酸与二氧化碳的反应形成与硫结合的单硫碳酸盐.
- 硫酸碳酸盐的电化学氧化,释放二氧化碳并再生捕获剂.
- 使用NMR,FTIR和电化学分析进行表征.
- 计算量子化学计算.
主要成果:
- 形成了一个稳定的与硫结合的单硫碳酸添加物 (硫酸).
- 在离子液体和有机溶剂中成功证明了电化学捕获释放循环.
- 量子化学计算显示了二氧化碳和甲之间强大的结合能量 (-66.3 kJ mol-1).
- 这项研究代表了硫结合终端硫碳酸盐的电化学行为.
结论:
- 描述的电化学循环提供了一种新且潜在的有效的二氧化碳捕获和释放方法.
- 酸作为有效的捕获剂,与二氧化碳形成稳定的添加物.
- 这种基于硫的方法为传统的二氧化碳捕获策略提供了有希望的替代方案.
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