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Updated: Mar 8, 2026

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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通过替代效应微调多轨道导体的性能

Aaron Mailman1, Joanne W L Wong1, Stephen M Winter1

  • 1Department of Chemistry, University of Waterloo , Waterloo, Ontario N2L 3G1, Canada.

Journal of the American Chemical Society
|January 25, 2017
PubMed
概括

将一个基组纳入bisdithiazolyl基稳定了LUMO,增强了电荷传输和降低了库伦壁垒. 这导致了Mott绝缘基态,可以调整到压力下的金属行为.

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