在多孔固体中的合成后复兴
1Department of Chemistry and Biochemistry, University of California, San Diego , La Jolla, California 92093, United States.
Journal of the American Chemical Society
|January 25, 2017
概括
金属有机框架 (MOF) 是多功能材料,可以进行固态化学反应. "合成后的复兴"可以精确地将MOF转化为复杂的功能性晶体结构.
科学领域:
- 材料科学
- 固态化学
- 共价化学
背景情况:
- 金属有机框架 (MOF) 已成为化学领域的重要研究领域.
- MOFs将共价化学从离散分子扩展到扩展结构.
- 它们作为固态中异质有机转换的支架.
研究的目的:
- 探索MOF作为化学转化平台的发展.
- 突出MOF化学中的"合成后复兴"概念.
- 展示创建新型晶体,多孔材料的方法.
主要方法:
- 使用MOF作为异质有机转换的支架.
- 使用单晶转化为单晶的材料修饰.
- 应用各种后合成方法,包括修饰,去保护,交换,插入和聚合.
主要成果:
- 展示MOF作为固态化学反应的多功能平台.
- 成功实施MOF衍生物的"合成后复兴".
- 创建具有增强复杂性和功能的晶体,多孔固体.
结论:
- MOF为设计和合成先进材料提供了独特的机会.
- 合成后的策略可以精确控制MOF的结构和特性.
- MOF的领域不断扩大,通过化学转换提供了新的功能.
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