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C ENDOR脂氧酶基质复合物的光谱揭示了道化C-H激活的结构基础

Masaki Horitani1, Adam R Offenbacher, Cody A Marcus Carr

  • 1Department of Chemistry, Northwestern University , Evanston, Illinois 60208, United States.

Journal of the American Chemical Society
|January 26, 2017
PubMed
概括

酶C-H激活需要接近道. 这项研究揭示了大豆氧酶通过构造性采样实现这一点,而不是使用Mn2+和ENDOR光谱的不寻常的活性位点结构.

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