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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Kinetics describes the rate and path by which a reaction occurs. In contrast, thermodynamics deals with state functions and describes the properties, behavior, and components of a system. It is not concerned with the path taken by the process and cannot address the rate at which a reaction occurs. Although it does provide information about what can happen during a reaction process, it does not describe the detailed steps of what appears on an atomic or a molecular level. On the other hand,...
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Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
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Catalysis02:50

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The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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石墨到钻石:运动选择性的起源

Yao-Ping Xie1,2, Xiao-Jie Zhang1, Zhi-Pan Liu1

  • 1Collaborative Innovation Center of Chemistry for Energy Material, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Key Laboratory of Computational Physical Science, Department of Chemistry, Fudan University , Shanghai 200433, China.

Journal of the American Chemical Society
|February 8, 2017
PubMed
概括
此摘要是机器生成的。

在轻度压缩下, 石墨会变成六角钻石, 而不是立方钻石. 这种令人惊的选择性是由新的原子层结构解释的,

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科学领域:

  • 材料科学
  • 固态物理
  • 晶体学

背景情况:

  • 在静态压缩下,石墨的固体相转变是热力学上有利于立方钻石.
  • 然而,实验观察表明,即使在温和的条件下 (15GPa) 也倾向于六角形钻石形成.

研究的目的:

  • 阐明控制石墨到钻石相位过渡的原子级机制.
  • 解释在轻微静态压缩下六角钻石比立方钻石形成的优势.

主要方法:

  • 全球潜在能量表面的探索,以确定低能量的中间结构.
  • 石墨-钻石过渡路径的定量运动分析.

主要成果:

  • 确定七种对过渡动力学至关重要的低能介质结构.
  • 由于连贯的石墨/六角钻石接口,六角钻石在石墨矩阵内容易核化.
  • 六角钻石的传播动力比立方钻石快得多.

结论:

  • 六角钻石所观察到的选择性是动力控制的,而不是热力学驱动的.
  • 一致的接口促进了六角钻石的快速核化和生长.
  • 由于缺乏连贯的核位,立方钻石的形成速度明显较慢,并且经常与六角钻石的生长混合.