介面分子定向对矿太阳能电池功率转换效率的影响
Minyu Xiao, Suneel Joglekar, Xiaoxian Zhang1
1CAS Key laboratory of Standardization and Measurement for Nanotechnology, Chinese Academy of Sciences Center for Excellence in Nanoscience, National Center for Nanoscience and Technology , Beijing 100190, China.
Journal of the American Chemical Society
|February 8, 2017
概括
控制矿太阳能电池中埋藏的接口的分子方向显著影响性能. 与躺着的方向相比,边缘聚烯定位提高了功率转换效率 (PCE) 的两倍.
科学领域:
- 材料科学
- 化学物理
- 可再生能源
背景情况:
- 在接口上的电荷载体动态对于平面异质连接太阳能电池的性能至关重要.
- 了解埋藏的介面分子结构对于设备优化至关重要.
- 现有的表征方法缺乏对埋藏界面的分子层面洞察力.
研究的目的:
- 在埋藏的矿/洞运输层接口探测分子结构.
- 将表面分子结构与矿太阳能电池性能相关联.
- 研究孔输送层结构在装置效率中的作用.
主要方法:
- 使用总频率生成振动光谱 (SFG),是一种表面/接口敏感的非线性振动技术.
- 在矿太阳能电池中控制了聚烯 (PT) 孔输送层 (HTL) 的结构.
- 改变PT衍生物的基侧链长度以影响界面方向.
主要成果:
- 在埋藏的矿/PT HTL接口成功探测了分子结构.
- 边缘 (正常的接口) PT 定向导致功率转换效率 (PCE) 超过躺下 (触角) 定向的两倍.
- 在PT衍生品上较短的基侧链促进了边缘导向和更高的PCE.
结论:
- 表面分子结构,特别是PT方向,显著影响矿太阳能电池PCE.
- 在埋藏界面上的边缘PT定位增强了电荷载体动态和设备性能.
- 定制HTL分子结构提供了一条优化矿太阳能电池效率的途径.
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